0

Full Content is available to subscribers

Subscribe/Learn More  >

Graphical User Interface With Reverse-Engineering of the Cyclic Voltammetry Method for Electrochemical Processes of Used Nuclear Fuel

[+] Author Affiliations
Samaneh Rakhshan Pouri, Supathorn Phongikaroon

Virginia Commonwealth University, Richmond, VA

Paper No. ICONE24-60439, pp. V005T15A026; 6 pages
doi:10.1115/ICONE24-60439
From:
  • 2016 24th International Conference on Nuclear Engineering
  • Volume 5: Student Paper Competition
  • Charlotte, North Carolina, USA, June 26–30, 2016
  • Conference Sponsors: Nuclear Engineering Division
  • ISBN: 978-0-7918-5005-3
  • Copyright © 2016 by ASME

abstract

This work focuses on an interactive reverse-engineering program design for the cyclic voltammetry (CV) method to help elucidating, improving, and providing robustness in detection analysis in the absence of complete experimental data sets during an electrorefining process of used nuclear fuel reprocessing. The work has been implemented into a Graphical User Interface (GUI) of the commercial software MATLAB allowing an individual user to directly control and make adjustments to support material detection and accountability. Analyzing and reconstructing the CV plots for uranium (U) in a LiCl-KCl molten salt at 500°C under different scan rates and at 1, 2.5, 5, 7.5, and 10 wt% have been accomplished. These test values provide the current (amp) versus potential (V) and concentration of each species (mol/cm3) versus the operating time (s) graphs under different specified conditions. The computational code uses the electrochemical fundamentals coupling with various experimental values existing in the literature such as the diffusion coefficients, formal potentials, reversible/irreversible time duration for reverse engineering of the CV technique. The user needs to specify only the desired concentration of uranium and the scan rate. All other experimental data sets for each condition have been stored in the code and can be used to interpolate between the existence data. The developed routine can be used to detect the peaks at the reversible and irreversible parts despite deficiencies of experimental data in a very short run time (around one minute) with an adequate selected time interval of approximately 0.08 second. Results indicate that the model can trace the current versus potential graph with a low root-meant-square (RMS) error compared to the experimental reported in literature. The concentration of each species at the reversible and irreversible of anodic and cathodic sides can be calculated and are shown based on increasing time which provided a good view of the whole process.

Copyright © 2016 by ASME

Figures

Tables

Interactive Graphics

Video

Country-Specific Mortality and Growth Failure in Infancy and Yound Children and Association With Material Stature

Use interactive graphics and maps to view and sort country-specific infant and early dhildhood mortality and growth failure data and their association with maternal

NOTE:
Citing articles are presented as examples only. In non-demo SCM6 implementation, integration with CrossRef’s "Cited By" API will populate this tab (http://www.crossref.org/citedby.html).

Some tools below are only available to our subscribers or users with an online account.

Related Content

Customize your page view by dragging and repositioning the boxes below.

Related eBook Content
Topic Collections

Sorry! You do not have access to this content. For assistance or to subscribe, please contact us:

  • TELEPHONE: 1-800-843-2763 (Toll-free in the USA)
  • EMAIL: asmedigitalcollection@asme.org
Sign In