0

Full Content is available to subscribers

Subscribe/Learn More  >

Exploring Lithium-Ion Intensity and Distribution via a Time-of-Flight Secondary Ion Mass Spectroscopy

[+] Author Affiliations
Cheng-Kai ChiuHuang, Chuanzhen Zhou, Hsiao-Ying Shadow Huang

North Carolina State University, Raleigh, NC

Paper No. IMECE2013-63013, pp. V010T11A077; 5 pages
doi:10.1115/IMECE2013-63013
From:
  • ASME 2013 International Mechanical Engineering Congress and Exposition
  • Volume 10: Micro- and Nano-Systems Engineering and Packaging
  • San Diego, California, USA, November 15–21, 2013
  • Conference Sponsors: ASME
  • ISBN: 978-0-7918-5639-0
  • Copyright © 2013 by ASME

abstract

For high rate-capability and low cost lithium-ion batteries, the prevention of capacity loss is one of major challenges facing by lithium-ion batteries today. During electrochemical processes, lithium ions diffuse from and insert into battery electrodes accompanied with the phase transformation, where ionic diffusivity and concentration are keys to the resultant battery capacity. In the current study, we first compare voltage vs. capacity curves at different C-rates (1C, 2C, 6C, 10C). Second, lithium-ion distributions and intensity are quantified via the Time-of-Flight Secondary Ion Mass Spectroscopy (ToF-SIMS). The result shows that voltage vs. capacity relations are C-rate dependent and larger hystereses are observed in the higher C-rate samples. Detailed quantification of lithium-ion intensity for the 1C sample is conducted. It is observed that lithium-ions are distributed uniformly inside the electrode. Therefore, the current study provides a qualitative and quantitative data to better understand C-rate dependent phenomenon of LiFePO4 battery cells.

Copyright © 2013 by ASME

Figures

Tables

Interactive Graphics

Video

Country-Specific Mortality and Growth Failure in Infancy and Yound Children and Association With Material Stature

Use interactive graphics and maps to view and sort country-specific infant and early dhildhood mortality and growth failure data and their association with maternal

NOTE:
Citing articles are presented as examples only. In non-demo SCM6 implementation, integration with CrossRef’s "Cited By" API will populate this tab (http://www.crossref.org/citedby.html).

Some tools below are only available to our subscribers or users with an online account.

Related Content

Customize your page view by dragging and repositioning the boxes below.

Related eBook Content
Topic Collections

Sorry! You do not have access to this content. For assistance or to subscribe, please contact us:

  • TELEPHONE: 1-800-843-2763 (Toll-free in the USA)
  • EMAIL: asmedigitalcollection@asme.org
Sign In