0

Full Content is available to subscribers

Subscribe/Learn More  >

Using Multiscale Modeling to Predict Material Response of Polymeric Materials

[+] Author Affiliations
Richard V. Beblo, Lisa Mauck Weiland

University of Pittsburgh, Pittsburgh, PA

Paper No. SMASIS2009-1333, pp. 189-196; 8 pages
doi:10.1115/SMASIS2009-1333
From:
  • ASME 2009 Conference on Smart Materials, Adaptive Structures and Intelligent Systems
  • Volume 1: Active Materials, Mechanics and Behavior; Modeling, Simulation and Control
  • Oxnard, California, USA, September 21–23, 2009
  • Conference Sponsors: Aerospace Division
  • ISBN: 978-0-7918-4896-8 | eISBN: 978-0-7918-3857-0
  • Copyright © 2009 by ASME

abstract

Presented is a multiscale modeling method applied to light activated shape memory polymers (LASMP). LASMP are a new class of shape memory polymer (SMP) being developed for applications where a thermal stimulus is undesired. Rotational Isomeric State (RIS) theory is used to build a molecular scale model of the polymer chain yielding a list of distances between the predicted cross-link locations, or r-values. The r-values are then fit with Johnson probability density functions and used with Boltzmann statistical mechanics to predict stress as a function of strain of the phantom network. Junction constraint theory is then used to calculate the stress contribution due to interactions with neighboring chains, resulting in previously unattainable numerically accurate Young’s modulus predictions based on the molecular formula of the polymer. The system is modular in nature and thus lends itself well to being adapted for specific applications. The results of the model are presented with experimental data for confirmation of correctness along with discussion of the potential of the model to be used to computationally adjust the chemical composition of LASMP to achieve specified material characteristics, greatly reducing the time and resources required for formula development.

Copyright © 2009 by ASME

Figures

Tables

Interactive Graphics

Video

Country-Specific Mortality and Growth Failure in Infancy and Yound Children and Association With Material Stature

Use interactive graphics and maps to view and sort country-specific infant and early dhildhood mortality and growth failure data and their association with maternal

NOTE:
Citing articles are presented as examples only. In non-demo SCM6 implementation, integration with CrossRef’s "Cited By" API will populate this tab (http://www.crossref.org/citedby.html).

Some tools below are only available to our subscribers or users with an online account.

Related Content

Customize your page view by dragging and repositioning the boxes below.

Related eBook Content
Topic Collections

Sorry! You do not have access to this content. For assistance or to subscribe, please contact us:

  • TELEPHONE: 1-800-843-2763 (Toll-free in the USA)
  • EMAIL: asmedigitalcollection@asme.org
Sign In