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A Dry-Borohydride/Injected-Hydrogen-Peroxide Fuel Cell

[+] Author Affiliations
George H. Miley, Nie Luo, Kyu-Jung Kim

University of Illinois, Urbana, IL

Paper No. FuelCell2010-33259, pp. 119-125; 7 pages
doi:10.1115/FuelCell2010-33259
From:
  • ASME 2010 8th International Conference on Fuel Cell Science, Engineering and Technology
  • ASME 2010 8th International Fuel Cell Science, Engineering and Technology Conference: Volume 1
  • Brooklyn, New York, USA, June 14–16, 2010
  • Conference Sponsors: Advanced Energy Systems Division
  • ISBN: 978-0-7918-4404-5 | eISBN: 978-0-7918-3875-4
  • Copyright © 2010 by ASME

abstract

The design and testing of a 20-W (average power with short pulses to 45W) prototype fuel cell is presented. This cell is intended as an auxiliary power supply for a small robotic vehicle. The energy density exceeds 300 Watt-hour/kg. This cell is essentially a dry-borohydride/injected-hydrogen-peroxide fuel cell. This enables extremely long shelf life prior to use. The anode utilizes dry NaBH4 for storage while the cathode chamber is empty during storage. The initiation of cell operation is done by injection of the oxidizer, an aqueous H2 O2 solution (stored in a separate container) to the cathode side of the fuel cell. The ionic conduction required for membrane operation is initially helped by the H2 O content from the H2 O2 solution. Once the electrochemical reaction starts, more water is generated as the reaction product and this continues to maintain a good ionic conductance over the run time of the cell. Continued operation is done with auxiliary fuel tanks to maintain very long run time when required. Once a run is over, the cell can be drain, flushed clean and returned to storage waiting for the next mission. The experimental details of such a cell stack are described in this paper.

Copyright © 2010 by ASME
Topics: Fuel cells , Hydrogen

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