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Characteristics of Solidified Products Containing Radioactive Molten Salt Waste

[+] Author Affiliations
In-Tae Kim, Hwan-Seo Park, Yong-Zun Cho, Kwang-Wook Kim, Seong-Won Park, Eung-Ho Kim

Korea Atomic Energy Research Institute, Daejeon, South Korea

Paper No. ICEM2007-7303, pp. 315-319; 5 pages
  • The 11th International Conference on Environmental Remediation and Radioactive Waste Management
  • 11th International Conference on Environmental Remediation and Radioactive Waste Management, Parts A and B
  • Bruges, Belgium, September 2–6, 2007
  • Conference Sponsors: Nuclear Division and Environmental Engineering Division
  • ISBN: 978-0-7918-4339-0 | eISBN: 0-7918-3818-8
  • Copyright © 2007 by ASME


For a treatment of molten salt wastes generated from a pyroprocessing of oxide spent fuel, we had suggested a stable chemical route, named GRSS (Gel-Route Stabilization & Solidification), and a subsequent consolidation method. By using this method, a series of monolithic wasteforms with different conditions were fabricated, and then their physicochemical properties were investigated. A simulated salt containing 90wt% LiCl, 6.8wt% CsCl, and 3.2wt% SrCl2 was treated with a gel-forming material system, Si/Al/P = 0.4/0.4/0.2 and 0.35/0.35/0.3, and the gel-products were treated at 1100C° after mixing with borosilicate glass powder, where the salt loadings were about 16∼20wt%. The solidified products had a density of 2.3∼2.35g/cm3 , a micro-hardness of 4.69∼4.72GPa, a glass transition temperature of 528∼537C°, and a thermal expansion coefficient of 1.65×10−7 ∼3.38×10−5 /C°. Leaching results by the PCT-A method revealed leached rates, 10−3 ∼10−2 g/m2 day and 10−4 ∼10−3 g/m2 day for Cs and Sr, respectively. From the long-term ISO leaching test, the 900day-leached fraction of Cs and Sr predicted by a semi-empirical model were 0.89% and 0.39%. The leaching behaviors indicated that Cs would be immobilized into a Si-rich phase while Sr would be in a P-rich phase. The experimental results revealed that the GRSS method could be an alternative method for a solidification of radioactive molten salt wastes.

Copyright © 2007 by ASME



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