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Detailed and Reduced-Chemistry Descriptions for Ignition and Detonation of Propane

[+] Author Affiliations
M. V. Petrova, B. Varatharajan, F. A. Williams

University of California at San Diego, La Jolla, CA

Paper No. GT2003-38057, pp. 37-53; 17 pages
doi:10.1115/GT2003-38057
From:
  • ASME Turbo Expo 2003, collocated with the 2003 International Joint Power Generation Conference
  • Volume 2: Turbo Expo 2003
  • Atlanta, Georgia, USA, June 16–19, 2003
  • Conference Sponsors: International Gas Turbine Institute
  • ISBN: 0-7918-3685-1 | eISBN: 0-7918-3671-1
  • Copyright © 2003 by ASME

abstract

The chemistry of autoignition of propane is studied with the objective of developing reduced chemistry descriptions. A detailed mechanism of 165 reaction steps among 38 chemical species is identified. This mechanism is reduced to a short mechanism of 34 steps, by deleting steps that are unnecessary. In the short mechanism, steady-state species are identified for deriving a systematically reduced mechanism. Good agreement with measured shock-tube ignition times is found.

Copyright © 2003 by ASME

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