0

Full Content is available to subscribers

Subscribe/Learn More  >

The Use of Vanadium Modified Materials for Reactor Fabrication

[+] Author Affiliations
Les Antalffy, George Miller, Kenneth Kirkpatrick

Fluor, Sugar Land, TX

Fausto Fusari

Belleli Energy, Mantova, Italy

A. Bertoni

Elettrotermochimica S.r.l., Padova, Italy

Paper No. PVP2005-71610, pp. 287-299; 13 pages
doi:10.1115/PVP2005-71610
From:
  • ASME 2005 Pressure Vessels and Piping Conference
  • Volume 7: Operations, Applications, and Components
  • Denver, Colorado, USA, July 17–21, 2005
  • Conference Sponsors: Pressure Vessels and Piping Division
  • ISBN: 0-7918-4192-8 | eISBN: 0-7918-3763-7
  • Copyright © 2005 by ASME

abstract

Vanadium modified 2 1/4Cr-1Mo and 3Cr-1Mo alloys used for the fabrication of hydroprocessing reactors offer a number of important advantages over the corresponding conventional alloys. These include increased resistance to hydrogen attack, a lower susceptibility to temper embrittlement, increased resistance to weld overlay disbonding and higher strength resulting in thinner and lighter reactors. Since the first vanadium modified 3Cr-1Mo reactors first went into service in the early 1990’s, vanadium modified alloys have gained acceptance and today more than one hundred and forty vanadium modified reactors and pressure vessels have been placed in service and are operating in severe process environments. Despite the excellent benefits of these materials, they also exhibit less desirable characteristics such as reduced weldability, higher hardnesses in the base metal, weld metal and heat affected zones and the need for higher post weld heat treatment (PWHT) temperatures. Additionally, these materials have a reduced notch toughness at lower temperatures especially in the as welded condition and require intermediate stress relieving (ISR) in lieu of dehydrogenation treatment (DHT) in restrained and highly stressed joints such as nozzle to shell and head welds. These materials also require extra care and effort to be taken during fabrication. The paper presents a serious weld metal cracking problem that occurred with vanadium modified materials during the installation of a nozzle in a restrained and highly stressed weld when only DHT was performed instead of the more beneficial ISR. This fabrication problem is provided as a typical example of problems that can occur during fabrication with vanadium modified materials, and points out that additional care must be taken during fabrication when using these materials. The paper identifies the main causes for the cracking using information based upon mechanical, metallurgical and stress analyses and suggests steps that may be taken to circumvent similar reoccurrences.

Copyright © 2005 by ASME
Topics: Manufacturing

Figures

Tables

Interactive Graphics

Video

Country-Specific Mortality and Growth Failure in Infancy and Yound Children and Association With Material Stature

Use interactive graphics and maps to view and sort country-specific infant and early dhildhood mortality and growth failure data and their association with maternal

NOTE:
Citing articles are presented as examples only. In non-demo SCM6 implementation, integration with CrossRef’s "Cited By" API will populate this tab (http://www.crossref.org/citedby.html).

Some tools below are only available to our subscribers or users with an online account.

Related Content

Customize your page view by dragging and repositioning the boxes below.

Related eBook Content
Topic Collections

Sorry! You do not have access to this content. For assistance or to subscribe, please contact us:

  • TELEPHONE: 1-800-843-2763 (Toll-free in the USA)
  • EMAIL: asmedigitalcollection@asme.org
Sign In